Hydrochlorination of Ruthenaphosphaalkenyls: Unexpectedly Facile Access to Alkylchlorohydrophosphane Complexes
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چکیده
منابع مشابه
Hydrochlorination of Ruthenaphosphaalkenyls: Unexpectedly Facile Access to Alkylchlorohydrophosphane Complexes
The novel ruthenaphosphaalkenyls [Ru{P=C(H)SiMe2R}Cl(CO)(PPh3)2] (R = p-C6H4CF3, Bu) have been prepared for the first time, and studied alongside precedent analogues (R = Me, Ph, p-tol) for their reactions with HCl. In contrast to chemistry defined for the tert-butyl congener [Ru{P=C(H)Bu}Cl(CO)(PPh3)2], which initially adds a single equivalent of HCl across the Ru-P linkage, all five silyl der...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2017
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.6b00829